How to retrieve private key from a profile [export from advanced menu gone]

The messages are likely sync messages, e.g. if you pin a chat they are sent. As for not being able to decrypt them, the reason is likely that Thunderbird still does not support SEIPDv2:

You can try to decrypt with GopenPGP or rPGP or Sequoia PGP: OpenPGP interoperability test suite

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