No chance to bring phone an PC into the same network. How to add 2nd device?

I have to add Deltachat for different domain-users on domain-PC, workgroup-laptop and phone.
Laptop has OpenVpn-Connection.
PC doesn’t have a camera.

Where do I set up the initial account to keep things (hopefully) simple?
How to add account to phone as 2nd device, if there is no way to add OpenVPN?

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